Saturday 15 February 2014

DI-DCO Solved Exam Paper with Explanation (RAJASTHAN) . 2012 Part-1


Q. l Mini Pill contains
a) Estrogen                                        b) Non Hormonal Contents
c) Progesterone                                 d) Estrogen and Progesterone
Ans 1. C   Progestogen-only pills or progestin-only pills (POP) are contraceptive pills that contain only synthetic progestogens (progestins) and do not contain estrogen. They are colloquially known as mini pills.
Q.2 Longer use of organic nitrates in Angina pectoris cause one of the following side effect
a) Hepatotoxicity        b) Tolerance                c) Aplastic anemia       d) Nepherotoxicity
Ans 2. B  The most specific medicine to treat angina is nitroglycerin. It is a potent vasodilator that makes more oxygen available to the heart muscle. After long-term use for chronic conditions, tolerance may develop in a patient, reducing its effectiveness.
Q.3 Zafirleucast is used as anti-asthmatic acts as
a) Prostaglandin antagonist                      b) Lipooxygenase Inhibitor
c) Cyclooxygenase inhibitor         d) Leukotrine receptor antagonist
Ans 3. D Zafirlukast is an oral leukotriene receptor antagonist (LTRA) for the maintenance treatment of asthma, often used in conjunction with an inhaled steroid and/or long-acting bronchodilator. Zafirlukast blocks the action of the cysteinyl leukotrienes on the CysLT1 receptors, thus reducing constriction of the airways, build-up of mucus in the lungs and inflammation of the breathing passages.
Q.4 Phloem does not contain
a) Phloem fibers  b) Sieve-tubes  c) Companion cells     d) Tracheids
Ans 4. D  Phloem tissue consists of: conducting cells, generally called sieve elements; parenchyma cells, including both specialized companion cells or albuminous cells and unspecialized cells; and supportive cells, such as fibres and sclereids.


Q.5 Group of plants of a species which have identical morphological characters but differ in their
chemical nature known as
a) Hybrids       b) Chemodemes    c) Polyploidy        d) Mutation
Ans 5. B  Chemodemes (Chemical Races)  are regarded as a group of plants of a species which have identical morphological characters but differ in their chemical nature.

Q.6 Which of the following is the major cause of drug instability?
a) Oxidation     b) Photolysis    c) Hydrolysis          d) Racemization
Ans 6. A Removal of an electropositive atom, radical or electron, or the addition of an electronegative atom or radical.”
Types:
Oxidation has two types
· Auto-oxidation
· Photo-oxidation
Auto-oxidation:
“Oxidation in which the oxygen present in the air is involved.”
This process proceeds slowly under the influence of atmospheric oxygen
e.g. Oil, fats & unsaturated compound can undergo auto- oxidation
Photo-oxidation:
“Oxidation in which removal of the electron is involved with out presence of O2.”
This type is less frequently encountered
e.g. It occurs in adrenaline, riboflavin & ascorbic acid etc.

Q.7 What is the unit of rate constant for zero order kinetics?
a) s-1            b) Mol L-1s-1      c) Mol L s-1        d) Mol-1L-1s
Ans 7. B Differential rate laws can take on many different forms, especially for complicated chemical reactions. However, most chemical reactions obey one of three differential rate laws. Each rate law contains a constant, k, called the rate constant. The units for the rate constant depend upon the rate law, because the rate always has units of mole L-1 sec-1 and the concentration always has units of mole L-1.
Zero-Order Reaction
For a zero-order reaction, the rate of reaction is a constant. When the limiting reactant is completely consumed, the reaction abrupts stops.
Differential Rate Law:       r = k
The rate constant, k, has units of mole L-1 sec-1.
For a zero-order reaction the half-life is given by

First-Order Reaction
For a first-order reaction, the rate of reaction is directly proportional to the concentration of one of the reactants.

Differential Rate Law:       r = k [A]

The rate constant, k, has units of sec-1.
Second-Order Reaction
For a second-order reaction, the rate of reaction is directly proportional to the square of the concentration of one of the reactants.

Differential Rate Law:       r = k [A]2

The rate constant, k, has units of L mole-1 sec-1.
Units
The units of the rate constant depend on the global order of reaction: If concentration is measured in units of mol·L−1 (sometimes abbreviated as M), then
  • For order (m + n), the rate coefficient has units of mol1−(m+n)·L(m+n)−1·s−1
  • For order zero, the rate coefficient has units of mol·L−1·s−1 (or M·s−1)
  • For order one, the rate coefficient has units of s−1
  • For order two, the rate coefficient has units of L·mol−1·s−1 (or M−1·s−1)
  • And for order three, the rate coefficient has units of L2·mol−2·s−1 (or M−2·s−1)

Q.8 Talc is used as glidant as ?
a) 5%             b) 10%              c) 15%                 d) 20%
Ans 8. A Talc=5% , Corn starch=5-10%
LUBRICANTS:
Magnesium Stearate (and Calcium Stearate):
Water Solubility: Insoluble
Conc. Use Range: 0.25 - 1.5%
Stearic Acid:
Water Solubility: Insoluble
Conc. Use Range:1 - 4%
Hydrogenated Vegetable Oil (Sterotex, Lubritab, Cutina):
Water Solubility: Insoluble
Conc. Use Range: 2 - 5%
Mineral Oil:
Water Solubility: Insoluble
Conc. Use Range: 1 - 3%
Polyethylene Glycol 4000 -6000 (PEG):
Water Solubility: Soluble
Conc. Use Range: 2 - 5%
Sodium Lauryl Sulfate (SLS):
Water Solubility: Soluble
Conc. Use Range: 2 - 3%
Glyceryl Palmitostearate (Precirol) & Glyceryl Behenate (Compitrol 888):
Water Solubility: Insoluble
Conc. Use Range: 2 - 5%
Sodium Stearyl Fumarate (Pruv):
Water Solubility: Soluble
Conc. Use Range: 0.5 - 2%

ANTIADHERANTS and GLIDANTS:
Talc:
Water Solubility: Insoluble
Conc. Use Range: 1-10%
The pure talc mineral is a hydrous magnesium silicate, Mg3Si3O10(OH)2

Fumed Silicon Dioxide (Cab-o-sil):
Water Solubility: Insoluble
Conc. Use Range: As anti-adherent, 1-2% As glidant, 0.1 - 0.5%

Q.9 The surface material from a tablet that is sticking to and being removed from the tablets
surface by a punch is known as
a) Capping        b) Lamination       c) Sticking           d) Picking
Ans 9. D
Capping→Partial or complete removal of top or bottom portion of the tablet (Due to air entrapment)
Lamination→Separation of tablet into two or more distinct layers (Due to air entrapment)
Sticking→Adhesion of tablet material to a die wall ( Due to excessive moisture)
Picking→Material from a tablet that is sticking to and being removed from the tablets
surface by a punch
Mottling→Unequal colour distribution on a tablet

Q.10 Zeatin
a) Auxin         b) Gibberlin    c) Cytokinin       d) Abscisic acid
Ans 10. C  Zeatin is a plant hormone derived from the purinebase called adenine. Zeatin belongs to the family of plant-growth hormones called cytokinins and was discovered in immature corn kernels from the genus Zea. It promotes growth of lateral buds and when sprayed on meristems stimulates cell division to produce bushier plants.
Zeatin and its derivatives are the active ingredient in coconut milk, which causes plant growth.
Zeatin has several anti-aging effects on human skin fibroblasts.


Q.11 Cap Aloe is
a) Aloe Barbadensis   b) Aloe Perryi    c) Aloe Vera     d) Aloe ferox
Ans 11. D


                                                                       (Aloe ferox)
Aloe ferox, also known as Cape Aloe, Bitter Aloe, Red Aloe  and Tap Aloe,is a species of aloe indigenous to South Africa's Western Cape, Eastern Cape.
Aloe Barbadensis→Barbados or Curacao aloes
Aloe Perryi→Socotrine aloes


Q.12 Most toxic constituent of Red Squill is
a) Scillaren A    b) Scillaren B c) Scilliroside   d) Glucoscillaren
Ans 12. C Drimia maritima (syn. Urginea maritima) is a species of flowering plant in the family Asparagaceae, subfamily Scilloideae (formerly the family Hyacinthaceae). This species is known by several common names, including squill, sea squill, sea onion, and maritime squill. It may also be called red squill, particularly a form which produces red-tinged flowers instead of white.It is native to southern Europe, western Asia, and northern Africa.
Uses
The plant has been used as a poison and as a medicinal remedy. The main active compounds are cardiac glycosides, including unique bufadienolides such as glucoscillarene A, proscillaridine A, scillarene A, scilliglaucoside and scilliphaeoside. The plant can have a cardiac glycoside content of up to 3%. Scilliroside, the most important of the toxic compounds, is present in all parts of the plant.
Poison
The plant has also been used as a poison. It is very bitter, so most animals avoid it. Rats, however, eat it readily, and then succumb to the toxic scilliroside.


Q.13 Rutin is rhamanoglucoside of
a) Scopoletin    b) Hesperitin      c) Esculetin         d) Quercetin
Ans 13. D Rutin, also called rutoside, quercetin-3-O-rutinoside and sophorin, is the glycoside between the flavonol quercetin and the disaccharide rutinose (α-L-rhamnopyranosyl-(1→6))-β-D-glucopyranose).
Rutin is one of the phenolic compounds found in the invasive plant species Carpobrotus edulis and contributes to the antibacterial and antioxidant properties of the plant.
Its name comes from the name of Ruta graveolens, a plant that also contains rutin.
Health effectsWhile a body of evidence for the effects of rutin and quercetin is available in mice,  rats,  hamsters,  and rabbits,  as well as in vitro studies,  no clinical studies directly demonstrate significant, positive effects of rutin as dietary supplement in humans.
  • Rutin inhibits platelet aggregation,  as well as decreases capillary permeability, making the blood thinner and improving circulation.
  • Rutin shows anti-inflammatory activity in some animal and in vitro models.
  • Rutin inhibits aldose reductase activity.  Aldose reductase is an enzyme normally present in the eye and elsewhere in the body. It helps change glucose into the sugar alcohol sorbitol.
  • Recent studies show rutin could help prevent blood clots, so could be used to treat patients at risk of heart attacks and strokes.
  • Some evidence also shows rutin can be used to treat hemorrhoids, varicosis, and microangiopathy.
  • Rutin increases thyroid iodide uptake in rats without raising serum T3 or T4.
  • Rutin is also an antioxidant; compared to quercetin, acacetin, morin, hispidulin, hesperidin, and naringin, it was found to be the strongest. However, in other trials, the effects of rutin were lower or negligible compared to those of quercetin.
Hydroxyethylrutosides, synthetic hydroxyethyl acetylations of rutin, are used in the treatment of chronic venous insufficiency.

Q.14 Castor oil is
a) Non drying oil         b) Semi drying oil                   c) Drying oil                d) Super drying oil
Ans 14. B
Semi-drying oil►
A semi-drying oil is an oil which partially hardens when it is exposed to air. This is as opposed to a to drying oil, which hardens completely, or a non-drying oil, which does not harden at all. Oils with an iodine number of 115-130 are considered semi-drying. Examples →
  • Corn oil
  • Cottonseed oil
  • Sesame oil
  • Grape seed oil
Non-drying oil► A non-drying oil is an oil which does not harden when it is exposed to air. This is as opposed to a to drying oil, which hardens completely, or a semi-drying oil, which partially hardens. Oils with an iodine number of less than 115 are considered non-drying. Examples →
  • Almond oil
  • Babassu oil
  • Coconut oil
  • Cocoa butter
  • Macadamia oil
  • Olive oil
  • Peanut oil
  • Nahar Seed oil
  • Baobab Oil
Drying oil,  unsaturated fatty oil, either natural (such as linseed oil) or synthetic, that when spread into a thin film becomes hard, tough, and elastic upon exposure to the air. Drying oils are used as vehicles in paints, varnishes, and printing inks. Examples → nut oils—e.g., hempseed and linseed oils
Q.15 Animal wool fat is
a) Fat                b) Lipid           c) Wax             d) Fixed oil
Ans 15. C Lanolin also called wool wax or wool grease, is a yellow waxy substance secreted by the sebaceous glands of wool-bearing animals.

Q.16 Hyoscyamus is
a) Belladona           b) Henbane    c) Stramonium      d) Duboisia
Ans 16. Hyoscyamus is a small genus of flowering plants in the nightshade family, Solanaceae. The eleven species it contains are known generally as the henbanes.  All of them are toxic. A poisonous Eurasian plant (Hyoscyamus niger) having an unpleasant odor, sticky leaves, and funnel-shaped greenish-yellow flowers. It is a source of the drug hyoscyamine.

Q.17 Murexide test is used for identification of
a) Purine          b) Tropane               c) Quinoline         d) Indole
Ans 17. A Caffeine (also the other purine alkaloids) gives murexide colour reaction. Caffeine is taken in a petridish to which hydrochloric acid and potassium chlorate are added and heated to dryness. A purple colour is obtained by exposing the residue to vapours of dilute ammonia. The purple colour is lost on addition of fixed alkali.

Q.18 Gas sterilization is done by using gas
a) Ethylene oxide b) Formaldehyde c) Nitrous oxide 
d) Acetaldehyde
Ans 18. A Ethylene oxide
Chemical formula:C2H4O
(EO or EtO) gas is commonly used to sterilize objects sensitive to temperatures greater than 60 °C and / or radiation such as plastics, optics and electrics. Ethylene oxide treatment is generally carried out between 30 °C and 60 °C with relative humidity above 30% and a gas concentration between 200 and 800 mg/l, and typically lasts for at least three hours. Ethylene oxide penetrates well, moving through paper, cloth, and some plastic films and is highly effective. EtO can kill all known viruses, bacteria and fungi, including bacterial spores and is compatible with most materials (e.g. of medical devices), even when repeatedly applied. However, it is highly flammable, toxic and carcinogenic with a potential to cause adverse reproductive effects. Ethylene oxide sterilizers requires biological validation and testing of every load, after sterilization installation, repairs or process failure. Biological testing or spore testing are paper filter saturated in millions of Bacillus atropheus known as Bacillus subtilis.
Q.19 Diazotization titration is not used for
a) Pyrimethamine        b) Sulphadiazine                     c) Sulfamethoxazole   d) Thiamine HCl
Ans 19. D      Diazotization Titrations
l  Aromatic primary amines react with sodium nitrite in acidic solutions to form diazonium salts.
l  C6H5NH2 + NaNO2+HCl            C6H5N2Cl+ NaCl + 2H2O
l  End point is indicated by the presence of small amounts of nitrous acid.
l  End point detection by two methods,
l  Visual end point
l  Amperometrically
l  Visual end point is indicated using starch iodide paper according to the formula
l  KI + HCl             HI + KCl
l  2HI + 2HNO2        I2 + 2NO + 2H2O
l  Amperometric method is using bright platinum electrodes. At the end point, permanent deflection of the galvanometer is observed. Usually 30 – 50mV of potential is applied.
Applications
Used in the determination of primary aromatic amines. May be used for the analysis of drugs such as benzocaine, dapsone, primaquine etc
Q.20 In gas chromatography column length is
a) 5-10 meter               b) 1-4 meter                             c) 10-15 meter             d) 15-20 meter
Ans 20. B

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